关键词:
Dipterocarpaceae
Dammar resins
Gas chromatography-mass spectrometry
Biodegradation
Biomarkers
Triterpenoids
POLYCYCLIC AROMATIC-HYDROCARBONS
TRITERPENOID HYDROCARBONS
MASS-SPECTROMETRY
9TH-CENTURY ARAB
AUSTRALIAN COALS
INDIAN SHIPWRECK
SEDIMENTS
IDENTIFICATION
DIAZOMETHANE
DIAGENESIS
摘要:
Plant resins, and particularly dammars from the Dipterocarpaceae family, were widely used in the past, notably as part of caulking material. The organic composition of resins, already complicated, is not always preserved over time and can be considerably affected by ageing. Hence, their occurrence in archaeological items leads to the necessity to identify them taxonomically with precision. Resinous organic materials collected near and/or on wrecks discovered in South China Sea, supposed to contain dammar resins because of their geographical excavation context, were investigated by gas chromatography-mass spectrometry (GC-MS), together with freshly collected dammars, to establish taxonomic and alteration parameters allowing to identify dammar even in very altered samples or in mixtures together with other organic materials. This study specially focuses on three samples collected within or close to the M1J wreck, a Portuguese wreck lost in the Straight of Malacca during the 16th century. Our analyses establish that all three are made of dammar, two of them in association with pitch and bitumen. In addition, biodegradation biomarkers were detected in all these three samples, indicating that they were submitted to microbial degradation processes during their ageing. (C) 2009 Elsevier B.V. All rights reserved.